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Slather the pesto on both sides of the pork chops, then place them into a dish, and cover them with plastic wrap. Allow the pork chops to marinate for a minimum of 4 hours, up to overnight.
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When you're ready to cook, heat a grill to medium-low heat and oil the grates.
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Season the pork chops with salt and pepper and lay them onto the grill.
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Grill the pork chops for 12-15 minutes, or until the juices run clear near the bone.
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Serve hot.